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Integrated circuits (ICs) are always pin-numbered counting counterclockwise from the uppermost pin of the case s left-hand row, with the IC situated vertically, top up (the top of an IC is indented or notched to aid in pin identification). However, for the sake of clarity (fewer crossing wires on the drawing), schematic diagrams of ICs often rearrange pins emerging from the IC. So don t expect the counterclockwise numbering to hold true in schematics. The good news is that IC pins on a schematic drawing are all numbered, and the diagram will show where they re all meant to go. In some digital circuits, unused IC pins must still be connected, or tied, to ground. You ll remember that such pins are all meant to be connected to the negative (-) side of the power supply. The letters IC identify integrated circuits in schematic diagrams, and they are followed either by the actual IC designation (as in IC LM3909, and you d better hope not it s extinct) or by a number referring you to the master parts list.

3-143

(continued)

coupling and/or disproportionation with another propagating radical (or itself) or add monomer. Attack on the ring carbon yields radical XXIX, which can react with another

propagating radical (Eq. 3-144) to form the quinone XXX. The latter may itself be an inhibitor. An alternate route for radical XXIX is rearrangement to XXXI followed

3-144

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opposite directions for several years. After 1946 the differential declined almost steadily and finally, in 1960, became negative in another period of what were then considered high interest rates. After 1960, yield spreads became more erratic than they had been earlier in the century. After 1964 the yield curve became negative, sometimes sharply negative. Then suddenly in 1971 it became sharply positive and tended to remain positive until the late 1970 s except in the period of extreme market pressure in 1974. This positive curve is sometimes interpreted to mean a market forecast of still higher yields to come. Such a forecast proved to be correct as yields advanced to record levels in 1979 1981, during which time negative yield curves were common. Until 1989, when the curve became flat, it was generally positive, except that thirty-year yields were often less than twenty-year yields.

Diodes are one-way gates in electronics: They ll allow current to pass in one end and out the other, but not in reverse. In other words, diodes are polarized. On the component itself you ll find a printed band toward one end of its body, encircling the diode s cylinder. This band corresponds with the line at the tip of the arrowhead in the diode s schematic symbol. The arrow points in the direction the diode will allow electricity to pass through it, in the unmarked end and out the end marked by the band. So a diode held against the schematic symbol of itself will be correctly oriented when the band on the diode and the line at the diagram s arrowhead correspond (in the drawing, band and line would be at the diode s right-hand side). The letter D is used to identify a diode in a schematic diagram, usually followed by a number allowing the reader to refer to the master parts list for further identification.

3-145

by coupling or termination with other radicals. The overall stoichiometry (i.e., the value of y in Eqs. 3-139 and 3-140) between the number of kinetic chains terminated and the number of the original quinone molecules consumed varies considerably depending on the particular quinone and radical. Although y often is 1, both pathways (Eqs. 3-143 and 3-144/3-145) can yield y values larger than 1 (up to 2) depending on the reactivities of XXVIII and XXX. Polar effects appear to be of prime importance in determining the effect of quinones. p-Benzoquinone and chloranil (which are electron-poor) act as inhibitors toward electronrich propagating radicals (vinyl acetate and styrene) but only as retarders toward the electron-poor acrylonitrile and methyl methacrylate propagating radicals. A further observation is that the inhibiting ability of a quinone toward electron-poor monomers can be increased by the addition of an electron-rich third component such as an amine. Thus the presence of triethylamine converts chloranil from a very weak retarder to an inhibitor toward methyl methacrylate. Oxygen is a powerful inhibitor, as seen from the very large z values. Oxygen reacts with radicals to form the relatively unreactive peroxy radical that reacts with itself or another

Table 54 Yield Differentials in Basis Points According to Maturity: 1900 1989

3-146

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