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effect on molecular weight distribution, 86 87 Unpaired ion, 373 374 Unsaturated polyester, 118 120, 531 532 Urea-formaldehyde polymer, 126 128 UV, see Spectroscopic analysis Vapor pressure osmometry, 21 Vecta, 159 Verel, 308 Vespel, 152 Vestenamer, 591 Vinyl polymer, 304 306 Vinyl monomer, 4 6 Viscose rayon, 746 Viscosity, 22, 64 Viscosity-average molecular weight, 22. See also Molecular weight; Molecular weight distribution Viscosity effect, 488 489 Viton, 533 Vitri cation effect, 285 286 Volume of activation, 293 295 Vulcanizate, 742 Vulcanization of elastomers, 133, 738 742. See also Crosslinking Vygen, 306 Water-in-oil emulsion, 367 Weight-average functionality, 110 Weight-average molecular weight, 21 24. See also Molecular weight; Molecular weight distribution Weight-fraction, 21, 80 82 Wood, 745 Wool, 2 Wurtz coupling, 173 174 Xanthate, 330, 746 Xanthation, 745 746 Xerogel, 171 Xerography, 313 X-ray diffraction, 27 Xydar, 159 p-Xylylene, 311 313 Zero-order Markov model, 708 709 Ziegler or Ziegler-Natta initiator, see Coordination initiator; Stereoisomerism in polymers; Stereoselective polymerization Zip polymerization, 289 Zirconocene, 670 671 Zwitterion polymerization, 587 589, 605 606

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U 2wiA 2Mo pB Mo pB0 Mo 1 p2 p2 0 =2 B B 2-110

The term was the natural term of the transaction: from seed time to harvest, for example But since such a seed loan can often be made only once a year, it might have been a matter of indifference to both debtor and creditor whether the term was six months or twelve months The earliest historical customs relating to credit and interest, which will now be examined, should not be considered the direct successors of the primitive customs and rates which have just been cited Most, and probably all, civilizations that were able to record their own histories were.

The weight-average molecular weight, obtained by a weight averaging of wA , wB , and wB0 , is given by

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Crystals set frequency in circuitry (often used to tune a master pitch or to clock general circuit activity). Their schematic symbol is close to that of the capacitor (each sets up pulses at assigned frequencies, if you re looking for a tie-in to support the similar graphic representations). There are two main types of crystal packages common to circuitry: the ceramic, looking like it could be just about anything (capacitors, resistors, and other components also come housed in such indistinct packages); and canned crystals, looking like small metal cans, rounded off a bit at the corners. Crystals are almost always given away by their rating, printed plainly on the side in MHz (megahertz). The letter X or the letters XTL might be present to identify a crystal, but you might find a code for the crystal (often including its MHz) as the only label present.

Mw wA wB wB0 2 4 4 2-111

Mo Mw 4 ( 2 pB pB0 2 1 p2 p2 0 =2 B B ) 2-112

Table 53A Yields by Maturity Basic Yields of Prime Corporate Bonds: 1900 1975 (February Data)

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on substitution for wA, wB , and wB0 . The number-average molecular weight, obtained by dividing the total number of moles of reactants initially present divided by the total present at any time, yields

Mn Mo 1 pA 2-29

THE UNITED STATES IN THE TWENTIETH CENTURY: 1946 1990

( Canned ) FIGURE C-5

For the case where B and B0 groups have the same reactivity:

g b 2-114

PDI 2 a 2 2 b2 g2 =2a 2-115

(continued)

Equation 2-115 yields PDI as a function of conversion in a straightforward manner without having to solve differential equations to obtain the number- and weight-average molecular weight distributions. One need only take a set of b values and then calculate the corresponding g, a, and PDI values from Eqs. 2-114 and 2-115. The limit of PDI at complete conversion pA 1; a 0 is 2 as for the Flory distribution. The Macosko-Miller method has also been applied to other polymerizations, including the A plus A0 0 system. In B B addition to being a simpler method for obtaining the average properties compared to the Flory and similar methods, it more readily allows an evaluation of the effect of various reaction parameters such as unequal group reactivity or nonstoichiometric amounts of reactants on M n , M w , and PDI (see Sec. 2-7e).

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