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This became a reductio ad absurdum of the old gift custom more generally described as Indian giving (13) 6 In Namaland, in Southwest Africa, cattle and beads were the original currencies Debts were incurred in cattle (no rates quoted), and the difficulty of repayment often led to cattle raids into neighboring states (14) In the Belgian Congo, brass rods were used extensively as a standard of deferred payment Credit was frequently granted by native traders, and tribal law gave creditors extensive power to collect In the French Sudan cattle were used until recently as currency for large transactions Cattle loans were granted free of interest, but if a cow which was lent had a calf, the calf and the cow was claimed by the creditor (15) Similarly, in Uganda and French Equatorial Africa cattle and sheep were the bases of credit.

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vinyl ether, 703 See also Coordination initiator; Stereoisomerism in polymers Stereospeci c polymerization, see Stereoselective polymerization, Steric effect: chain polymerization, 277 279 copolymerization, 496 497, 508, 511 hyperbranched polymer, 176 177 polymer reaction, 732 733 ring-opening polymerization, 545 546, 567, 577 Sterically-hindered pyridine, 376 Stoichiometric imbalance, 75 79 Stoichiometric ratio, 75 79 Stopped- ow method, 393 396 Stopper, 185 Strain, 34 Strength, 34 Stress-strain properties, see Mechanical properties Structural isomerism, 144, 619 620 Structural repeating unit, 12 Structural unit, 50 Styrene-acrylonitrile copolymer, 529 530, 738 Styrene-1,3-butadiene rubber, 351 353, 529 530, 738 Styrene-maleic anhydride copolymer, 143, 530 Styrofoam, 304 Styron, 304 Substituted ethylene, 4 6 Subunit, 12 Sulfur, 600, 739 742 Sulfur heterocyclic polymerization, 588 589 Sulfur nitride polymerization, 600 Sulfur polymerization, 600 Sulfur vulcanization, 739 742 Super acid, 769 Super glue, 414 Superactive initiator, 645 Supercritical carbon dioxide, 183 Supercritical uid, 183, 309 Support, 760 765 Supported initiator, 645, 664 665. See also Stereoselective polymerization Surfactant, 298, 352 353, 363 364 Surlyn, 531 Suspension polymerization, 297 298 Suspension stabilizer, 298 Switchboard model, 25 27 Syn addition, 654 655 Syncatalyst, 375 Syndioregic, 203 Syndioselective polymerization, 624, 641, 652 654

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Syndiotactic, 622 Syndiotactic dyad, 624 Syndiotactic placement, 637 Syndiotactic polymer, 622 624. See also Stereoisomerism in polymers; Stereoselective polymerization Syndiotactic triad, 636 Tacticity, 622 624, 635 637 Taft equation, 505 Tail, 144 Tail addition in initiation, 235 Tail-to-tail structure, see Head-to-head structure Tandem polymerization, 681 Tapered copolymer, 437 438. See also Gradient copolymer TA process, 93 Tecno on, 533 Tedlar, 310 Te on, 310 Tefzel, 310 Telechelic polymer, 140, 155 156, 321, 439 440, 759 Telomer, 238 239 Template polymerization, 287 289, 299 TEMPO, 325 328 Tensile strength, 34 Terathane, 568 Terluran, 530 Terminal model: copolymerization, 466 469, 505 506, 513 515 stereochemistry, 709 710 Termination, see Chain termination Terpolymerization, 464, 485 487 Terylene, 94 Tetrad, 636 Texin, 142 Thermal analysis, 27 Thermal initiation, 220 221, 226 227, 273 Thermal transition, 29 32 Thermally stable polymer, see High-temperature polymer Thermodynamics of polymerization: carbonyl monomer, 444 445 chain copolymerization, 515 518 radical chain reaction, 275 281, 296 ring-opening reaction, 545 546, 566 567 step polymerization, 65 69, 73 74, 81 Thermoplastic, 105 Thermoplastic elastomer, 142 143 Thermoplastic polyurethane, 142 143 Thermoset polymer, 105, 117 118

= + (Polarized electrolytic) FIGURE C-4

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Thermotropic liquid crystal, 157 159 Thietane polymerization, 588 589 Thiirane polymerization, 588 589 Thiokol, 135 Threo, 625 626, 632 Threodiisotactic polymer, 625 626, 632 Threodisyndiotactic polymer, 625 626, 632 Threshold pressure, 296 Tie molecule, 26 27 Tight ion pair, 373 374. See also Ion pair Topochemical polymerization, 184. See also Solid-state polymerization; Transport polymerization Torlon, 153 Torsional strain, 71 TPE, see Thermoplastic elastomer TPU, see Thermoplastic polyurethane Trade name, 16 Traditional Ziegler-Natta initiators, 640 665 Trans addition, 654 655 s-Trans conformation, 690 691 Transannular strain, 72 Transformation reaction, 324, 443 Transition probabilities, 469 470 Translational diffusion, 283 286 Transoid, 690 691 Trans-polymer, 629 634. See also Stereoisomerism in polymers; Stereoselective polymerization Transport polymerization, 311 313 Triad, 636 Triad tacticity, 636 637 Trifunctional monomer, 56 63 Trioxane polymerization, 561 562 Triphase catalyst, 770 Triple-ion, 435 436 Trommsdorff effect, 214, 282 289, 364 Twaron, 100 Two-ended living anion, 423 Two-prepolymer technique, 139 140 Two-strand polymer, see Ladder polymer Tybrene, 530 Ultem, 153 Ultimate elongation, 34 Ultimate strength, 34 Ultimate unit, 464 Ultrathene, 530 Ultraviolet-visible spectroscopy, see Spectroscopic analysis Unequal functional group reactivity: effect on crosslinking, 112 115 effect on rate and molecular weight, 54 63

In the former the creditor expected every third new birth as interest 7 In Northern Siberia, at least until recently, domesticated reindeer served as money Loans were granted in reindeer Among the Kirghiz of Siberia, horses and sheep served as money and were loaned out The usual interest for such loans was 100% (16) These scraps of primitive interest rates are in fact all a part of modern history, not of ancient history or of the prehistory of credit Inferences from them should be made with caution They do, however, serve to illustrate the actual operation of primitive credit in kind and in very general terms show the type and magnitude of return the creditor often expected In most cases per annum rates were not conventional and our translation into modern credit terms is forced.

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