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However, for polypropylene under inert conditions the results show an increase of activation energy E with an increase of heat ramp rate The thermal decomposition temperature increases with increase in the ramp rate In any case the amount of heat of pyrolysis is relatively larger under oxidative condition than in inert condition except for the high heating rate of polystyrene The temperature dependence of heat of pyrolysis depends on the material properties The reason for high endothermic heat of pyrolysis at high heating rate for polystyrene in oxidative condition is as follows In the experiments we chose approximately constant mass and constant heat ow so that at different heating rate the sample receives different amounts of air per gram of sample It is to be noted that the temperature of the air is at the sample temperature at the given condition.

In real practice excess air levels may be 50 100% of the stoichiometric amount Our results obtained can still be used under these conditions The results show that at higher heating rate the ratio of required amount of air to that provided to combust the polystyrene is not so high So the assumption of constant partial pressure of oxygen becomes weak Thus the correlation between.

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Figure 12-6: As an irregular hotspot region takes shape, you can pull in the region s shape to fit the image beneath it.

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The amount of cell refinement near boundaries is controlled by the 'refinement level' parameter which is specified by the user This parameter dictates how many times a global cell may be cut in two A refinement level of 1 allows a global cell to be subdivided into a maximum of 2 x 2 x 2 refined cells, level 2 allows 4 x 4 x 4 subdivision, level 3 allows 8 x 8 x 8 etc The example in Fig 42 uses level 2 refinement Refinement of a cell is not applied uniformly in all three directions, eg a cell may be divided in the x direction but not the y or z directions.

soft drink bottle recycling systems The bottle is manufactured with a ve layer structure: PET/EVOH/PET/EVOH/PET The EVOH is required to obtain suf cient oxygen barrier for the product The absence of a tie (adhesive) layer between the PET and EVOH causes the material to delaminate when the bottles are ground and the material washed during recycling The EVOH material is mostly removed during the wash and rinse processes The small amount that remains is not detrimental to PET properties In December, 2000, a new report from the Plastic Redesign Project examined the effect of new plastic packaging innovations on plastic bottle recycling, with a speci c focus on whether trends in bottle design could further erode the prices paid to local recycling programs for plastic bottles because of the expense in handling new structures [23].

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Mentioned as design changes that have facilitated plastics recycling are elimination of the base cup in 2-liter soft drink bottles, substitution of PET for PVC bottles, substitution of EVOH for PVC liners in closures for carbonated beverages, and development of LDPE shrink labels to substitute for glued-on labels on milk bottles The major concerns identi ed are the increasing use of colors other than green in PET bottles and the growth in use of PET bottles that contain non-PET components to enhance barrier properties Both of these developments increase the cost of processing recovered plastic bottles and also affect the value of the recovered material The study estimates that the intermediate processor s cost to manually separate another color from clear and green PET bottles would be about 6 cents per pound, and if mechanical sorting is available, it would be about 15 cents per pound.

The value of green PET ake currently averages 189% lower than clear PET ake The value of new colors, such as amber from beer bottles and blue from water bottles, would be lower, averaging perhaps 11 cents per pound less than clear..

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